Analytical Chemistry Technology  ·  Level 6
Physics Principles
Chapter 9: Apply principles of nuclear physics
📚 11 Topics
⚑ What you will be able to do

By the end of this chapter, you will be able to:

  • Safely produce and use X-rays by following the nuclear physics manufacturer’s manual correctly.
  • Accurately detect radioactive elements using specialized detection systems.
  • Carefully observe all safety precautions when working with radioactive elements according to safety regulations.
  • Correctly apply radioactive radiations using key nuclear physics principles.

Mastering these skills helps you work confidently and safely with nuclear technology, an important part of many modern industries.

9.1 Production of X-rays

X-rays are electromagnetic waves of very short wavelength, about 10⁻¹³ m to 10⁻⁸ m, carrying high energy photons that can pass through materials opaque to light. They were discovered by Wilhelm Röntgen in 1895. X-rays are produced when fast-moving electrons are suddenly stopped by striking a metal target: most of the electrons' kinetic energy becomes heat, but a small fraction is given out as X-ray photons. The device that does this is the X-ray tube, found in hospital radiography units, airport baggage scanners and analytical instruments such as X-ray diffractometers and X-ray fluorescence spectrometers. Example: the radiology department of a sub-county hospital in Kiirua takes chest X-rays with a tube run at about 100 kV, set by the radiographer for each patient.

Parts of an X-ray tube

Part Description Function
Evacuated glass or metal envelope High vacuum inside Lets electrons travel to the target without colliding with gas molecules
Cathode (filament) Tungsten coil heated by a low voltage supply (about 6 to 12 V) Emits electrons by thermionic emission
Focusing cup Concave metal around the filament, at cathode potential Focuses the electrons into a narrow beam
Anode (target) Tungsten (high melting point, high atomic number) set in a copper block; or copper, molybdenum or rhodium in analytical tubes Stops the electrons and emits X-rays
High voltage supply 20 kV to 150 kV between cathode and anode Accelerates the electrons to high speed
Cooling system Oil bath, fins, water cooling or a rotating anode Removes the large amount of heat produced at the target
Lead shield with window Lead casing with a thin beryllium or glass window Absorbs stray X-rays and lets out a useful beam

How X-rays are produced

  1. Thermionic emission: Current through the filament heats it to a high temperature, and electrons are emitted from its surface.
  2. Acceleration: The high voltage between cathode and anode accelerates the electrons across the vacuum to very high speeds.
  3. Focusing: The focusing cup directs the electrons onto a small area of the target, the focal spot.
  4. Impact: The electrons strike the target and are rapidly slowed and stopped by the target atoms.
  5. Energy conversion: About 99 % of their kinetic energy becomes heat in the target; only about 1 % is converted into X-ray photons.
  6. Emission: The X-rays leave the target in all directions; the shielding lets only the useful beam out through the window.

Energy of the electrons and X-rays

An electron accelerated through a potential difference V gains kinetic energy:

KE = eV

If all of this is converted into a single photon, the photon has the maximum energy and therefore the minimum wavelength:

eV = hc ÷ λmin, so λmin = hc ÷ (eV)

Worked example: an X-ray tube operates at 30 kV. Find the kinetic energy of the electrons arriving at the target and the shortest wavelength of the X-rays produced. (e = 1.6 × 10⁻¹⁹ C, h = 6.626 × 10⁻³⁴ J s, c = 3.0 × 10⁸ m/s)

KE = eV = 1.6 × 10⁻¹⁹ × 30,000 = 4.8 × 10⁻¹⁵ J

λmin = hc ÷ (eV)

λmin = (6.626 × 10⁻³⁴ × 3.0 × 10⁸) ÷ (4.8 × 10⁻¹⁵)

λmin = 4.14 × 10⁻¹¹ m (0.0414 nm)

Controlling the X-ray beam

  • Intensity (quantity): Controlled by the filament current (the tube current, in mA). A hotter filament emits more electrons, so more X-ray photons are produced, without changing their energy.
  • Penetrating power (quality): Controlled by the accelerating voltage (kV). A higher voltage gives faster electrons, higher energy photons and shorter wavelengths, which penetrate further.
  • Exposure: Set by the tube current multiplied by the exposure time (mA s).
  • Filtration: Thin aluminium filters absorb the low energy X-rays that would only be absorbed by the skin, reducing the patient's dose.

Heat in the X-ray tube

Because about 99 % of the electron energy becomes heat, the target gets extremely hot. A tube at 100 kV and 20 mA receives 100,000 × 0.020 = 2,000 W, of which about 1,980 W is heat. The target is therefore made of tungsten (melting point 3,422 °C), set in copper to conduct the heat away, and in powerful tubes the anode is a rotating disc so that the heat is spread over a ring rather than a single spot.

Properties of X-rays

  • Travel in straight lines at the speed of light: 3.0 × 10⁸ m/s in a vacuum.
  • Not deflected by electric or magnetic fields: They carry no charge.
  • Penetrate matter: Pass through soft tissue, paper and wood, but are absorbed by dense, high atomic number materials such as bone and lead.
  • Ionise gases: They knock electrons out of atoms, which makes them harmful to living cells.
  • Affect photographic film and cause fluorescence: The basis of X-ray images.
  • Are diffracted by crystals: Their wavelength is similar to the spacing of atoms, the basis of X-ray crystallography.
The rest of this chapter
🔒

Create a free account to open more of this chapter.

Free: practical guides, quick cards, workplace scenarios and more.

Create a free account
🔒9.2 Types of X-rays

X-rays are classified in two ways. By their penetrating power they are hard or soft, which depends on the accelerating voltage of the tube and decides what they are used for. By the way they are produced in the target they are continuous (bremsstrahlung) or ch…

🔒9.3 Application of X-rays

X-rays are used wherever there is a need to see inside objects without opening them, to destroy unwanted cells, or to identify and measure the atoms and crystal structures of materials. Their uses rest on their properties: they penetrate matter to different de…

🔒9.4 Types of radioactivity

Radioactivity is the spontaneous disintegration of unstable atomic nuclei, during which they emit radiation (alpha particles, beta particles or gamma rays) and change into more stable nuclei. It was discovered by Henri Becquerel in 1896 when uranium salts fogg…

🔒9.5 Elements of radioactivity

Many elements have radioactive isotopes, but three are especially important for study: thorium and uranium, the heavy natural radioactive elements whose very long half-lives mean they have been decaying since the Earth formed, and carbon-14, a light radioisoto…

🔒9.6 Properties of radio-active materials

Radioactive materials are substances containing unstable nuclei that decay and give out ionising radiation. Their behaviour differs in important ways from ordinary chemical substances: decay happens on its own, cannot be speeded up or slowed down by any ordina…

🔒9.7 Types of radioactive radiations

Radioactive materials give out three main types of radiation, named by Ernest Rutherford after the first three letters of the Greek alphabet: alpha (α), beta (β) and gamma (γ). They differ in their nature, charge, mass, speed, ionising power and penetrating po…

🔒9.8 Half-lives of radioactive elements

The half-life of a radioactive isotope is the time taken for half of the radioactive nuclei in a sample to decay, or equivalently for the activity (or corrected count rate) of the sample to fall to half its starting value. Because decay is random but the fract…

🔒9.9 Uses of radioactivity

Radioisotopes are used in medicine, industry, agriculture, research and analysis because their radiation can be detected in extremely small amounts, penetrates materials to known depths, kills cells and micro-organisms, and decays at a fixed rate. The choice o…

🔒9.10 Hazards associated with radioactive material

Radiation from radioactive materials and X-ray machines is ionising: as it passes through living tissue it knocks electrons out of atoms and breaks chemical bonds, including those in DNA, the molecule that controls the cell. Cells can be killed, can fail to di…

🔒9.11 Safety precautions on X-rays and radio-active elements

Safety precautions for X-rays and radioactive materials aim to keep every person's radiation dose as low as reasonably achievable (ALARA) and always below the legal limits, and to prevent radioactive material from spreading or getting into the body. Protection…

Am I competent?

At the start of this chapter we promised you would be able to:

  • Safely produce and use X-rays by following the nuclear physics manufacturer’s manual correctly.
  • Accurately detect radioactive elements using specialized detection systems.
  • Carefully observe all safety precautions when working with radioactive elements according to safety regulations.
  • Correctly apply radioactive radiations using key nuclear physics principles.

Tick each one you can genuinely do.

So, are you there yet?

You're competent when you can confidently do 50% or more of what this chapter promised.

Sign in to record how you're doing.